A Selective Synthesis of the 1,3,4-Triphospholide Anion
收藏acs.figshare.com2023-06-02 更新2025-03-22 收录
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资源简介：
[Mg2(μ-Cl)3(THF)6][2,5-(CtBu)2-1,3,4-P3] and
K[2,5-(CtBu)2-1,3,4-P3] are formed quantitatively from
reduction of the tricyclic-triphosphorus compound ClP3(CtBu)2 with Mg or K; the mechanistic insights gained
from these studies lead to a new and “economic” synthesis of the [2,5-(CtBu)2-1,3,4-P3]- anion from the phosphalkyne tBuC⋮P.
通过将三环三磷化合物ClP3(CtBu)2与Mg或K进行还原反应，定量地制备了[Mg2(μ-Cl)3(THF)6][2,5-(CtBu)2-1,3,4-P3]和K[2,5-(CtBu)2-1,3,4-P3]；从这些研究中获得的机制见解引领了一种新颖且‘经济’的合成方法，即从磷炔tBuC⋮P出发制备[2,5-(CtBu)2-1,3,4-P3]阴离子。
提供机构：
ACS Publications
