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η3‑Furfuryl and η3‑Thienyl Complexes of Palladium and Platinum of Relevance to the Functionalization of Biomass-Derived Furans

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Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/_sup_3_sup_Furfuryl_and_sup_3_sup_Thienyl_Complexes_of_Palladium_and_Platinum_of_Relevance_to_the_Functionalization_of_Biomass_Derived_Furans/2497318
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A number of cationic and neutral η3-furfuryl complexes of palladium and platinum were prepared, including one with a ligand derived from fructose, 5-chloromethylfurfural. The complexes were studied by variable-temperature and heteronuclear correlation NMR spectroscopy, as well as single-crystal X-ray crystallography. Analogous η3-thienyl complexes could be prepared and detected in solution by NMR, but could not be isolated due to facile decomposition.
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2016-02-20
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