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Antiferromagnetism in a Technetium Oxide. Structure of CaTcO3

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Figshare2016-02-23 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Antiferromagnetism_in_a_Technetium_Oxide_Structure_of_CaTcO_sub_3_sub_/2691508
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The technetium perovskite CaTcO3 has been synthesized. Combining synchrotron X-ray and neutron diffraction, we found that CaTcO3 is an antiferromagnetic with a surprisingly high Neel temperature of ∼800 K. The transition to the magnetic state does not involve a structural change, but there is obvious magnetostriction. Electronic structure calculations confirm the experimental results.
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2016-02-23
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