Facile Insertion of Rh and Ir into a Boron–Phenyl Bond, Leading to Boryl/Bis(phosphine) PBP Pincer Complexes
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https://figshare.com/articles/dataset/Facile_Insertion_of_Rh_and_Ir_into_a_Boron_Phenyl_Bond_Leading_to_Boryl_Bis_phosphine_PBP_Pincer_Complexes/2077354
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资源简介:
The
unexpectedly facile insertion of Rh or Ir into a B–Ph
bond (reversible for Rh) converts a borane/bis(phosphine) precursor
into a boryl/bis(phosphine) PBP pincer ligand. Interconversions between
the boryl/borane/borate central functionality are demonstrated in
reactions with dihydrogen.
创建时间:
2016-01-29



