Metal-Free Iodine(III)-Promoted Synthesis of Isoquinolones
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https://figshare.com/articles/dataset/Metal_Free_Iodine_III_Promoted_Synthesis_of_Isoquinolones/2232889
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资源简介:
A metal-free oxidative cycloaddition
reaction of substituted benzamides
and alkynes has been developed for the synthesis of isoquinolones
by using bis(trifluoracetoxy)iodobenzene (PIFA) and trifluoroacetic
acid (TFA). Under mild conditions, a wide variety of isoquinolones
were conveniently prepared via oxidative annulation of simple N-methoxybenzamide and diarylacetylene or aryl/alkyl acetylene
derivatives in yields up to 87%.
创建时间:
2016-02-16



