Platinum(IV) Complexes with Chelating N-Heterocyclic Carbene Ligands
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https://figshare.com/articles/dataset/Platinum_IV_Complexes_with_Chelating_N_Heterocyclic_Carbene_Ligands/2744470
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资源简介:
Platinum(II) complexes with one or two chelating bis(NHC) ligands have been oxidized by bromine as well as iodobenzene dichloride to provide the corresponding platinum(IV) carbene complexes in good yields under very mild reaction conditions. All compounds have been fully characterized by 1H and 13C NMR spectroscopy and in three cases also by solid-state structures. The NMR spectra of the novel Pt(IV) complexes show significantly shifted signals compared to their Pt(II) precursor complexes.
创建时间:
2010-08-09



