A Unique Organolanthanide Cluster Containing Bulky Cyclooctatetraenyl Ligands
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https://figshare.com/articles/dataset/A_Unique_Organolanthanide_Cluster_Containing_Bulky_Cyclooctatetraenyl_Ligands/12067764
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资源简介：
The reaction of anhydrous PrCl3 with Li2(COT‘ ‘)
(COT‘ ‘ = 1,4-bis(trimethylsilyl)cyclooctatetraenyl) in THF
solution afforded an unprecedented cluster-centered Pr/Li
multidecker sandwich complex of composition [Pr(COT‘ ‘)]2[Pr2(COT‘ ‘)2]2Li2(THF)2Cl8 (1), in which a central cube of eight
Cl atoms is capped by two [Pr(COT‘ ‘)]+ half-sandwich and two
[Pr2(COT‘ ‘)2]2+ sandwich units as well as two [Li(THF)]+
moieties.
创建时间：
2007-09-10
