A Combined Computational and Spectroelectrochemical Study of Platinum-Bridged Bis-Triarylamine Systems

The
character of the electronic
transitions in the ultraviolet–visible–near infrared
(UV–vis–NIR) spectra of platinum-bis­(alkynyl) bridged,
bis-triarylamine mixed-valence systems trans-[Pt­(CCC6H4NAr2)2 (PR3)2]n+ (R = ethyl, Ar = C6H4CH3-4 (1) or C6H4OCH3-4 (2); R = Ph, Ar = C6H4CH3-4 (3) or C6H4OCH3-4 (4), n = 0, 1, 2) has been determined from a combination of spectroscopic
measurement and density functional theory calculations. The hybrid
functional BLYP35 in combination with a suitable solvent model (i.e.,
conductor-like screening model (COSMO)) has been used to model the
UV–vis–NIR and IR spectroscopic properties of [1–4]+, to confirm the description
of [1–4]+ as examples
of metal-bridged organic mixed-valence compounds, and to assign the
principal features of the electronic spectra, including the triarylamine-based
intervalence charge transfer transition located in the NIR region.
The successful modeling of the charge distribution within the system
demonstrates the utility of the BLYP35-COSMO protocol as a tool for
use in the study of intramolecular charge transfer properties in mixed-valence
complexes.