Detrifluoroacetylative in Situ Generation of Free 3‑Fluoroindolin-2-one-Derived Tertiary Enolates: Design, Synthesis, and Assessment of Reactivity toward Asymmetric Mannich Reactions
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https://figshare.com/articles/dataset/Detrifluoroacetylative_in_Situ_Generation_of_Free_3_Fluoroindolin-2-one-Derived_Tertiary_Enolates_Design_Synthesis_and_Assessment_of_Reactivity_toward_Asymmetric_Mannich_Reactions/3438122
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The discovery of detrifluoroacetylative in situ generation of a new type of fluorinated amide enolates derived from 3-fluoroindolin-2-one and their asymmetric Mannich additions with sulfinylaldimines bearing fluoroalkyl groups is reported, which afforded α-fluoro-β-(fluoroalkyl)-β-aminoindolin-2-ones containing C–F quaternary stereogenic centers with excellent yields and high diastereoselectivities.
创建时间：
2016-06-27
