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1,2-Rearrangements of β-Nitrogen-Substituted (Porphyrinato)rhodium(III) Ethyls

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https://figshare.com/articles/dataset/1_2_Rearrangements_of_Nitrogen_Substituted_Porphyrinato_rhodium_III_Ethyls/3285355
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资源简介:
(Porphyrinato)rhodium(III) ethyls containing β-nitrogen substituents have been showed to undergo clean, thermal 1,2-rearrangements into the α-nitrogen-substituted rhodium ethyls. The rates and the equilibrium positions were found to be dependent on the electronic nature of the N substituents. Complexes 1a−3a were characterized by X-ray crystallography.
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2016-05-06
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