Following Spin-Crossover - 3D Analysis of the electronic effects
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下载链接：
https://doi.esrf.fr/10.15151/ESRF-ES-2020721355
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资源简介：
This proposal seeks to investigate the spin-state and spin-crossover phenomena in metal-organic complexes using high-resolution single-crystal X-ray diffraction and Anomalous Dispersion Refinement (ADR) techniques. These phenomena are critical in fields like molecular electronics and data storage, yet current experimental techniques often lack the three-dimensional resolution needed for in-depth understanding. By utilizing ADR, we aim to resolve electron density distributions before and after a thermally induced spin-crossover,
achieving unprecedented precision in the analysis of the electronic and structural changes involved. The experiment will focus on Ru and Ag-based metal organic complexes, and will combine X-ray Absorption Spectroscopy (XAS) with diffraction data to provide new insights into the interplay between spin states and structural dynamics.
提供机构：
Institute of Inorganic Chemistry, Working group of Chemical Crystallography, Landoltweg 1, 52056, Aachen, DE; RWTH Aachen University, Institut fuer Anorganische Chemie, Landoltweg 1, 52074 Aachen, Germany
创建时间：
2028-01-01
