Data from: Salt-screened transition toward bulk-Like water dynamics near polymeric zwitterions

This dataset accompanies the article "Salt-Screened Transition toward
Bulk-Like Water Dynamics near Polymeric Zwitterions" by Shawn D.
Mengel, Audra J. DeStefano, Thomas Webber, Anton Semerdjiev, Songi Han,
and Rachel A. Segalman in ACS Macro Letters in 2024. The article
demonstrates how the diffusion of water molecules local to zwitterionic
surfaces is modulated by salt screening and hydration structure effects.
This dataset contains the necessary experimental data to reproduce the
main text and supporting figures. High performance liquid chromatographs,
mass spectra, electron paramagnetic resonance spectra and correlation
times, and Overhauser dynamic nuclear polarization parameters.

本数据集配套2024年发表于《ACS Macro Letters》的文章"Salt-Screened Transition toward Bulk-Like Water Dynamics near Polymeric Zwitterions"，作者为Shawn D. Mengel、Audra J. DeStefano、Thomas Webber、Anton Semerdjiev、Songi Han与Rachel A. Segalman。该文章阐明了盐屏蔽效应与水化结构作用如何调控两性离子聚合物表面附近局域水分子的扩散行为。本数据集包含复现论文正文与补充图表所需的全部实验数据，涵盖高效液相色谱数据、质谱谱图、电子顺磁共振谱图及相关弛豫时间，以及奥弗豪泽动态核极化（Overhauser dynamic nuclear polarization）参数。

搜集汇总

背景与挑战

背景概述

该数据集为2024年发表在ACS Macro Letters上的文章《Salt-Screened Transition toward Bulk-Like Water Dynamics near Polymeric Zwitterions》提供支持，包含实验数据以重现文章主文和支持图。数据涵盖高效液相色谱、质谱、电子顺磁共振谱和Overhauser动态核极化参数，用于研究盐屏蔽和溶剂化结构对两性离子表面水分子扩散的调节作用。数据集按文章图/表编号组织，包含多种技术测量结果，如k_sigma值、耦合因子和旋转相关时间等。