Mechanistic Analysis of Gold(I)-Catalyzed Intramolecular Allene Hydroalkoxylation Reveals an Off-Cycle Bis(gold) Vinyl Species and Reversible C–O Bond Formation

Mechanistic investigation of gold­(I)-catalyzed intramolecular allene hydroalkoxylation established a mechanism involving rapid and reversible C–O bond formation followed by turnover-limiting protodeauration from a mono­(gold) vinyl complex. This on-cycle pathway competes with catalyst aggregation and formation of an off-cycle bis­(gold) vinyl complex.