Oxidative Coupling of an Anionic Gallium(I) Carbene Analogue: Synthesis and Structural Characterization of an Unprecedented π-Cyclopentadienyl-Bridged Digallane Complex
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https://figshare.com/articles/dataset/Oxidative_Coupling_of_an_Anionic_Gallium_I_Carbene_Analogue_Synthesis_and_Structural_Characterization_of_an_Unprecedented_Cyclopentadienyl_Bridged_Digallane_Complex/3321571
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资源简介：
An unprecedented π-cyclopentadienyl-bridged
digallane complex, [{Ga[N(Ar)C(H)]2}2{μ-CpK(tmeda)2}]
(Ar = C6H3Pri2-2,6), incorporating the first structurally
characterized π-interaction with a Ga(II) center, results
from the oxidative coupling of an anionic gallium(I)
heterocycle with cyclopentadienylthallium(I). This compound can be regarded as an intermediate in the
nucleophilic attack of a digallane by the Cp- anion.
创建时间：
2016-05-06
