An Intramolecular Diels−Alder Strategy for the Asbestinins: Enantioselective Total Syntheses of 11-Acetoxy-4-deoxyasbestinin D and Asbestinin-12
收藏NIAID Data Ecosystem2026-03-06 收录
下载链接：
https://figshare.com/articles/dataset/An_Intramolecular_Diels_Alder_Strategy_for_the_Asbestinins_Enantioselective_Total_Syntheses_of_11_Acetoxy_4_deoxyasbestinin_D_and_Asbestinin_12/2952691
下载链接
链接失效反馈官方服务：
资源简介：
The enantioselective total syntheses of 11-acetoxy-4-deoxyasbestinin D and asbestinin-12 have been
completed. A glycolate aldol reaction provided a diene useful for ring-closing metathesis to form an
oxonene, which was ultimately employed as a template to execute a highly stereoselective intramolecular
Diels−Alder cycloaddition, forming the hydroisobenzofuran moiety. The absolute configuration of the
asbestinin subclass was confirmed via these synthetic efforts.
创建时间：
2016-02-27
