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Highly Enantioselective Copper-Catalyzed Propargylic Substitution of Propargylic Acetates with 1,3-Dicarbonyl Compounds

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Figshare2016-02-18 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Highly_Enantioselective_Copper_Catalyzed_Propargylic_Substitution_of_Propargylic_Acetates_with_1_3_Dicarbonyl_Compounds/2331646
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A chiral tridentate ketimine P,N,N-ligand has been successfully applied in the copper-catalyzed enantioselective propargylic substitution of propargylic acetates with a variety of β-dicarbonyl compounds, in which excellent enantioselectivities (up to >99% ee) and high yields have been obtained.
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2016-02-18
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