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Synthesis of a Rhodium Carbonyl Phosphaalkenyl–Phosphido Complex: A Phosphorus Congener of Schiff Base Type N,N′-Chelating Monoanionic Ligands

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Figshare2016-02-17 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Synthesis_of_a_Rhodium_Carbonyl_Phosphaalkenyl_Phosphido_Complex_A_Phosphorus_Congener_of_Schiff_Base_Type_N_N_Chelating_Monoanionic_Ligands/2312656
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A monoanionic, bidentate phosphaalkenyl–phosphido ligand was designed, synthesized, and used for the complexation of a rhodium carbonyl fragment. The characterization of the latter revealed delocalized π electrons on the phosphaalkenyl–phosphide moiety. The catalytic activity of this rhodium carbonyl complex has been demonstrated in a hydrosilylation reaction.
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2016-02-17
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