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Molecular Iodine Promoted Divergent Synthesis of Benzimidazoles, Benzothiazoles, and 2‑Benzyl-3-phenyl-3,4-dihydro‑2H‑benzo[e][1,2,4]thiadiazines

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Figshare2016-02-17 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Molecular_Iodine_Promoted_Divergent_Synthesis_of_Benzimidazoles_Benzothiazoles_and_2_Benzyl_3_phenyl_3_4_dihydro_2_i_H_i_benzo_i_e_i_1_2_4_thiadiazines/2300968
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An unprecedented formation of a new class of 2-benzyl-3-phenyl-3,4-dihydro-2H-benzo­[e]­[1,2,4]­thiadiazines has been discovered during the course of benzimidazole and benzothiazole synthesis, through the molecular iodine-mediated oxidative cyclization with a new C–N and S–N bond formation at ambient temperature.
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2016-02-17
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