Bimetallic Photoredox Catalysis: Visible Light-Promoted Aerobic Hydroxylation of Arylboronic Acids with a Dirhodium(II) Catalyst
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https://figshare.com/articles/dataset/Bimetallic_Photoredox_Catalysis_Visible_Light-Promoted_Aerobic_Hydroxylation_of_Arylboronic_Acids_with_a_Dirhodium_II_Catalyst/11591139
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资源简介：
We
report the use of a rhodium(II) dimer in visible light photoredox
catalysis for the aerobic oxidation of arylboronic acids to phenols
under mild conditions. Spectroscopic and computational studies indicate
that the catalyst Rh2(bpy)2(OAc)4 (1) undergoes metal–metal to ligand charge transfer
upon visible light irradiation, which is responsible for catalytic
activity. Further reactivity studies demonstrate that 1 is a general photoredox catalyst for diverse oxidation reactions.
创建时间：
2019-12-30
