Reaction between tBuMgCl and SnCl4, Illustrating the Solvent-Dependent Predominant Formation of Cl(tBu2Sn)nCl (THF, n = 1; Toluene, n = 2; Hexane, n = 3) and the Subsequent Wavelength-Selective Photochemical Transformation of n = 3 → 2 → 1
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https://figshare.com/articles/dataset/Reaction_between_sup_i_t_i_sup_BuMgCl_and_SnCl_sub_4_sub_Illustrating_the_Solvent_Dependent_Predominant_Formation_of_Cl_sup_i_t_i_sup_Bu_sub_2_sub_Sn_sub_i_n_i_sub_Cl_THF_i_n_i_1_Toluene_i_n_i_2_Hexane_i_n_i_3_and_the_Subsequent_Wavelength_Selective_Photo/2615605
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The addition of THF solutions of tBuMgCl to SnCl4 in varying solvents (S) results in a dramatic change of the predominant product obtained Cl(tBu2Sn)nCl (n = 1–3). For S = THF the product obtained was tBu2SnCl2, S = toluene, benzene yields Cl(tBu2Sn)2Cl, while for S = hexane the tristannane Cl(tBu2Sn)3Cl was isolated in 45% yield. The last compound is photochemically sensitive when irradiated at 350 nm to form Cl(tBu2Sn)2Cl. Irradiation of this latter material with a 254 nm lamp results in the formation of tBu2SnCl2.
创建时间：
2016-02-23
