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Auto-Tandem Palladium Catalysis: From Isoxazole to 2‑Azafluorenone

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NIAID Data Ecosystem2026-03-09 收录
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https://figshare.com/articles/dataset/Auto_Tandem_Palladium_Catalysis_From_Isoxazole_to_2_Azafluorenone/2106871
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An auto-tandem palladium catalysis from halogen-substituted isoxazoles and Michael acceptors is described. It involves two mechanistically distinct palladium-catalyzed reactions, a Heck reaction and a rearrangement, leading to 2-azafluorenones. It is the first example of palladium-catalyzed ring opening of isoxazoles and rearrangement of the β-imino ketone ring-opening product.
创建时间:
2016-02-12
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