Intramolecular α-Glucosaminidation: Synthesis of Mycothiol
收藏NIAID Data Ecosystem2026-03-06 收录
数据链接：
官方服务：
资源简介：
A protected cyclitol aglycon was tethered to an (N-arylsulfonyl)glucosamine donor by a methylene linker; the exclusively α-selective intramolecular glycosyation reaction was then initiated by electrophilic activation of the thioglycoside donor portion. Further transformations of the glycosylation product to give the M. tuberculosis detoxifier mycothiol and its oxidized congener, the disulfide mycothione, are detailed.
创建时间：
2010-06-04
