Table 1 in Lipoxygenase pathway in model bryophytes: 12 - oxo- 9 (13), 15 - phytodienoic acid is a predominant oxylipin in Physcomitrella patens

Table 1 The NMR spectral data (1 H-NMR, 1 H– 1 H–COSY, 1 H– 1 H-TOCSY, 1 H– 13 C-HSQC and 1 H– 13 C-HMBC) for compound 1 Me ester. 600 MHz, [2 H]benzene, 303 K. 6
Position13C chemical1H chemical shiftsHomonuclear andnumbershifts (ppm);(ppm); multiplicity;heteronuclear multiplefunctional groupcoupling constantbond correlations(Hz)1173.59; COOMeH2; H3234.03; CH22.13, t, 7.4 (H3)C1; C3; C4; H3; H4325.21; CH21.55, tt, 7.4 (H5)C1; C2; C4; H4; H5429.33; CH21.15, mC2; C3529.36; CH21.11, mC3629.82; CH21.08, mC7727.48; CH21.19, mC8; C9831.26; CH22.07, t, 7.8 (H7)C6; C7; C9; C10; C12;C13; H6; H7; H109171.85; CC12; C13; C14; C15;C16; H7; H8; H10; H111028.99; CH21.88, mC9; C11; C12; C13;C15; H8; H14; H151134.18; CH22.03, mC9; C10; C12; H14;H1512207.28; COH10; H11; H1413139.70; CH10; H11; H141421.85; CH23.06, d, 7.2 (H15)C9; C12; C13; C15;C16; H10; H11; H15;H16; H17; H1815126.15; CH5.48, dtt, 10.7 (H16),C14; H10; H11; H14;1.4 (H17)H17; H1816132.29; CH5.42, dtt, 7.0 (H17),H14; H17; H181.5 (H14)1721.07; CH22.21, dq, 7.5 (H18)C15; C16; C18; H14;H15; H16; H181814.44; CH30.98, tC16; C17; H14; H15;H16; H17(1)51.02; COOMe3.37; sC1, H2
[a] The value of coupling constant (J 5’,6’ = 10.9 Hz) was reconstructed by the computer simulation of the AB system signal. Попросить Булата проверить