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Methods for the Synthesis of Functionalized Pentacarboxycyclopentadienes

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https://figshare.com/articles/dataset/Methods_for_the_Synthesis_of_Functionalized_Pentacarboxycyclopentadienes/5276833
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Protocols for the synthesis of diverse pentacarboxycyclopentadienes are described. Starting from readily available pentacarbomethoxycyclopentadiene, transesterification offers single-step access to aliphatic ester derivatives, while treatment with amines produces mono- or diamides. For less nucleophilic alcohols, an alternative procedure involving the in situ generation and esterification of a putative cyclopentadiene pentaacid chloride has been developed.
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2017-08-03
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