Heterodinuclear Fe<sup>III</sup>Zn<sup>II</sup>-Bioinspired Complex Supported on 3-Aminopropyl Silica. Efficient Hydrolysis of Phosphate Diester Bonds
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Presented herein is the synthesis and characterization of a new FeIIIZnII complex containing a FeIII-bound phenolate with a carbonyl functional group, which was anchored to 3-aminopropyl-functionalized silica as the solid support. The catalytic efficiency of the immobilized catalyst in the hydrolysis of 2,4-bis(dinitrophenyl)phosphate is comparable to the homogeneous reaction, and the supported catalyst can be reused for subsequent diester hydrolysis reactions.
创建时间：
2016-02-25
