Effects of high pressure and temperature on acetoxy silicone rubber
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https://doi.esrf.fr/10.15151/ESRF-ES-2243044993
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Solid-state cooling based on caloric effects is a promising technology, presenting as an eco-friendlier and energy-efficient alternative to traditional refrigeration based on vapor compression gases. In this proposal, we intend to investigate the acetoxy silicone rubber (ASR) under high pressures (HP) at the ID15b beamline. ASR is a rubber-like polymer material that presents super-giant barocaloric effects due to a combination of conformational changes in chain structure and crystalline to amorphous phase transition. By using synchrotron X-day diffraction (XRD), ID15b beamline allows us to assess the phase transition as pressure increases, besides verifying the fraction of the crystalline phase. Understanding the structural changes in ASR is essential to the further development of barocaloric materials based on polymers. And, to the best of our knowledge, ASR has never been studied through XRD under HP.
提供机构:
Instituto de Fisica, Departamento de Eletronica Quantica, Rua São Francisco Xavier, 524, 20550-900, Rio de janeiro, BRASIL; Universidad de Valencia, Department of Applied Physics, Edificio de Investigacion C/Dr. Moliner 50 Burjassot, 46100, Valencia, SPAIN; Istituto italiano di Tecnologia, Material Characterization Facility, Via Morego, 30 - Genova, 16163, Genova, ITALY; Universidad de Valencia, Department of Applied Physics, Edificio de Investigacion, C/dr. Moliner 50 Burjassot, 46100 Valencia, Spain; Italian Institute of Technology, Lab Nanostructures, Via Morego 30, 16163, Genova, ITALY; Elettra Sincrotrone Trieste, Xpress beamline, Strada Statale 14 - Km 163,5, Area Science Park Bazovizza, 34149 Trieste, Italy; Universidade Federal de Sao Paulo, Departamento de Química, Rua São Nicolau, 210, Centro, 09913-030, Diadema, BRASIL
创建时间:
2028-01-01



