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Direct Tryptophols Synthesis from 2‑Vinylanilines and Alkynes via CC Triple Bond Cleavage and Dioxygen Activation

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Figshare2016-10-06 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Direct_Tryptophols_Synthesis_from_2_Vinylanilines_and_Alkynes_via_C_C_Triple_Bond_Cleavage_and_Dioxygen_Activation/3861000
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An unexpected metal-free CC triple bond cleavage, dioxygen activation, and reassembly into tryptophol derivatives has been developed. This chemistry provides a novel, simple, and efficient approach to highly valuable tryptophol derivatives from simple substrates under mild conditions. The mechanistic studies may promote the discovery of new methodologies through C–C bond cleavage and dioxygen activation.
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2016-10-06
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