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Synthesis and Structural Characterization of Cationic Rhenium(V) and Technetium(V) Dioxo Complexes Containing Four N-Heterocyclic Carbene Ligands

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NIAID Data Ecosystem2026-03-06 收录
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https://figshare.com/articles/dataset/Synthesis_and_Structural_Characterization_of_Cationic_Rhenium_V_and_Technetium_V_Dioxo_Complexes_Containing_Four_N-Heterocyclic_Carbene_Ligands/3613299
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Cationic dioxorhenium and dioxotechnetium complexes of the composition [MO2(L1)4]+ (L1 = 1,3-diisopropyl-4,5-dimethylimidazol-2-ylidene) have been prepared from various starting materials and studied spectroscopically and by X-ray crystallography. The metal−carbon distances range from 2.216(4) to 2.232(4) Å indicating mainly σ-bonding.
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2016-08-17
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