Construction of Furan Derivatives with a Trifluoromethyl Stereogenic Center: Enantioselective Friedel–Crafts Alkylations via Formal Trienamine Catalysis
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https://figshare.com/articles/dataset/Construction_of_Furan_Derivatives_with_a_Trifluoromethyl_Stereogenic_Center_Enantioselective_Friedel_Crafts_Alkylations_via_Formal_Trienamine_Catalysis/3978498
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资源简介：
An asymmetric Friedel–Crafts
alkylation reaction of 2-furfuryl
ketones with β-trifluoromethyl enones has been developed via
formal trienamine catalysis of a bifunctional primary amine-thiourea
substance derived from L-tert-leucine,
delivering the furan derivatives incorporating a stereogenic trifluoromethyl
(CF3) group in good to high yields with excellent enantioselectivity.
创建时间：
2016-10-17
