Preparation and Structure of a Tubular Addition Polymer: A True Synthetic Nanotube
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https://figshare.com/articles/dataset/Preparation_and_Structure_of_a_Tubular_Addition_Polymer_A_True_Synthetic_Nanotube/2562814
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资源简介：
The structure of a synthetic nanotube prepared by the
solid-state
polymerization of a stacked column of diacetylene-based macrocycles
has been determined. A polyether macrocycle monomer with two parallel
diacetylene functionalities was prepared. Its crystal structure revealed
that the compound crystallizes with structural parameters suitable
for topochemical polymerization. Slow annealing of a single crystal
for 35 days brought about a single-crystal-to-single-crystal polymerization
resulting in the first experimentally determined structure of a tubular
addition polymer.
创建时间：
2012-01-11
