Bioinspired Synthesis of Nortriterpenoid Propindilactone G
收藏Figshare2020-03-02 更新2026-04-28 收录
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https://figshare.com/articles/dataset/Bioinspired_Synthesis_of_Nortriterpenoid_Propindilactone_G/11944629
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资源简介：
A concise bioinspired synthesis of Schisandra nortriterpenoid propindilactone G has been accomplished from a readily accessible steroidal lactone. Key transformations include a Breslow remote functionalization, a Suárez remote radical functionalization, a ring expansion enabled by a Wagner–Meerwein rearrangement, a stereoinversion of a tertiary alcohol, and a biomimetic transesterification/oxa-Michael addition cascade. This work also provides experimental evidence of the putative propindilactone G biosynthesis pathway.
创建时间：
2020-03-02
