Syntheses of RuHCl(CO)(PAr3)3 and RuH2(CO)(PAr3)3 Containing Various Triarylphosphines and Their Use for Arylation of Sterically Congested Aromatic C–H Bonds
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https://figshare.com/articles/dataset/Syntheses_of_RuHCl_CO_PAr_sub_3_sub_sub_3_sub_and_RuH_sub_2_sub_CO_PAr_sub_3_sub_sub_3_sub_Containing_Various_Triarylphosphines_and_Their_Use_for_Arylation_of_Sterically_Congested_Aromatic_C_H_Bonds/3756693
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A series of ruthenium complexes, RuHCl(CO)(PAr3)3 and RuH2(CO)(PAr3)3, containing various triarylphosphines were synthesized. Screening of these complexes as catalysts for direct arylation of sterically congested ortho C–H bonds of aromatic ketones improved the yields of the arylation products.
创建时间:
2016-08-25



