Unique Radical Dearomatization and Two-Electron Reduction of a Redox-Active Ligand
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https://figshare.com/articles/dataset/Unique_Radical_Dearomatization_and_Two_Electron_Reduction_of_a_Redox_Active_Ligand/2483293
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资源简介：
The syntheses and characterizations of [Li4][(1,2-di-(tert-butyl)-dpp-BIAN)2] (7), (1,2-di-(tert-butyl)-dpp-BIAN) (8), and (1-(tert-butyl)-2-OH-dpp-BIAN) (9) are described.
Compound 7 was formed via a radical dearomatization,
two-electron reduction pathway that was accompanied by vicinal di-tert-butylation of the BIAN ligand backbone. Oxidation of 7 afforded a dearomatized vicinal di-tert-butyl substituted BIAN ligand (8). An analogous dearomatized
vicinal tert-butyl-hydroxy substituted BIAN ligand
(9) was also isolated in the course of mechanistic studies
related to the formation of 7.
创建时间：
2012-09-26
