Platinum(II) Enyne Cycloisomerization Catalysis: Intermediates and Resting States
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https://figshare.com/articles/dataset/Platinum_II_Enyne_Cycloisomerization_Catalysis_Intermediates_and_Resting_States/2876707
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资源简介：
In situ generated [(PPP)Pt][BF4]2 (PPP = triphos) catalyzes the cycloisomerization of 1,6-enyne-ols by initiative π-activation of the alkyne. This generates an isolable cationic Pt-alkenyl species, which subsequently participates in turnover-limiting protonolysis with in situ generated acid. This latter reactivity contrasts cationic Pt-alkyls, which are more difficult to protonolyze. Mechanistic studies on isolated Pt-alkenyls and deuterium labeling helped to elucidate the mechanistic details.
创建时间：
2009-02-23
