Highly Tactic Cyclic Polynorbornene: Stereoselective Ring Expansion Metathesis Polymerization of Norbornene Catalyzed by a New Tethered Tungsten-Alkylidene Catalyst
收藏Figshare2016-04-15 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Highly_Tactic_Cyclic_Polynorbornene_Stereoselective_Ring_Expansion_Metathesis_Polymerization_of_Norbornene_Catalyzed_by_a_New_Tethered_Tungsten_Alkylidene_Catalyst/3168583
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资源简介：
The tungsten alkylidyne [tBuOCO]WC(tBu) (THF)2 (1) reacts with CO2, leading to complete cleavage of one CO bond, followed by migratory insertion to generate the tungsten-oxo alkylidene 2. Complex 2 is the first catalyst to polymerize norbornene via ring expansion metathesis polymerization to yield highly cis-syndiotactic cyclic polynorbornene.
创建时间：
2016-04-15
