Catalyst Design of Vaska-Type Iridium Complexes for Highly Efficient Synthesis of π‑Conjugated Enamines
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https://figshare.com/articles/dataset/Catalyst_Design_of_Vaska_Type_Iridium_Complexes_for_Highly_Efficient_Synthesis_of_Conjugated_Enamines/2118313
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资源简介：
The
appropriate design of a ligand (L) in IrCl(CO)(L)2 (4) realized the efficient synthesis of π-conjugated
enamines possessing hole-transport properties. The iridium complex
with electron-withdrawing phosphorus ligands catalyzed the hydrosilylation
of amides to the corresponding silylhemiaminals, which were transformed
to the enamines by heat or by treatment with acids. High catalytic
efficiency (TON > 10,000) was achieved, which made it possible
for the residual iridium in the enamine product to be below 20 ppb.
创建时间：
2016-02-12
