A Bench-Stable, Single-Component Precatalyst for Silyl–Heck Reactions
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https://figshare.com/articles/dataset/A_Bench-Stable_Single-Component_Precatalyst_for_Silyl_Heck_Reactions/5455327
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资源简介：
Studies
of the silyl-Heck reaction aimed at identifying active
palladium complexes have revealed a new species that is formed in
situ. This complex has been identified as the palladium iodide dimer,
[(JessePhos)PdI2]2, which has been found to
be a competent single-component precatalyst for the silyl-Heck reaction.
This complex is easily prepared and is temperature, moisture, and
air stable. Additionally, this precatalyst provides higher activity
and greater reproducibility compared to previous systems.
创建时间：
2017-09-29
