Improved Synthesis of Larger Resorcinarenes
收藏NIAID Data Ecosystem2026-03-09 收录
下载链接：
https://figshare.com/articles/dataset/Improved_Synthesis_of_Larger_Resorcinarenes/3443360
下载链接
链接失效反馈官方服务：
资源简介：
The
synthesis of the larger resorcin[5 and 6]arene macrocycles [5]OMe and [6]OMe has been realized
by a Lewis acid-catalyzed condensation of 1,3-dimethoxy-2-methylbenzene
with paraformaldehyde in o-dichlorobenzene as the
solvent. The methoxy-resorcin[5 and 6]arenes were quantitatively demethylated
by treatment with BBr3 to obtain the corresponding macrocycles
with free OH groups. X-ray studies showed that in the solid state
both the conformation and the packing of [6]OMe and [5]OMe are driven by C–H···O,
C–H···π, and π···π
interactions.
创建时间：
2016-06-27
