Predicting the Diastereoselectivity of Rh-Mediated Intramolecular C−H Insertion
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https://figshare.com/articles/dataset/Predicting_the_Diastereoselectivity_of_Rh-Mediated_Intramolecular_C_H_Insertion/3656307
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资源简介：
Rhodium-mediated cyclization of the α-diazo ester
1 proceeds with high diastereoselectivity, to give
the
trisubstituted cyclopentane 5. A computational model
(ZINDO and Molecular Mechanics) based on our current
mechanistic understanding of the reaction is presented. This model
correctly predicts the dominant diastereomer
from the cyclization of 1 and the eight (Table ) other
α-diazo esters studied thus far.
创建时间：
2016-08-18
