Asymmetric Catalysis Using Self-Assembled Chiral Bidentate <i>P,P</i>-Ligands
收藏NIAID Data Ecosystem2026-03-06 收录
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资源简介：
A strategy is described for modular catalyst development based upon metal-directed self-assembly of bifunctional subunits around a structural metal to form a heteroleptic complex in which a second set of ligating groups are now suitably disposed to bind a second metal to form a catalytic site. A library of chiral diphosphites was prepared via metal-directed self-assembly and used in a simple asymmetric allylic amination, giving enantiomeric excesses as high as 97%.
创建时间：
2016-05-12
