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β‑Pyrrolopyrazino Annulated Corroles via a Pictet–Spengler Approach

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Figshare2016-07-11 更新2026-04-29 收录
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https://figshare.com/articles/dataset/_Pyrrolopyrazino_Annulated_Corroles_via_a_Pictet_Spengler_Approach/3471107
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Reaction of 2-amino-3-(pyrrol-1-yl)-5,10,15-tris­(4-tert-butylphenyl)­corrolato copper­(II) with arylaldehydes affords novel π-extended β,β′-pyrrolo­(1,2-a)­pyrazino-fused corroles via a Pictet–Spengler reaction. Corrole shows an unprecedented reaction pathway, leading to a mixture of phenyl-substituted and nonsubstituted pyrrolopyrazino annulated species as reaction products.
创建时间:
2016-07-11
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