β‑Pyrrolopyrazino Annulated Corroles via a Pictet–Spengler Approach
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https://figshare.com/articles/dataset/_Pyrrolopyrazino_Annulated_Corroles_via_a_Pictet_Spengler_Approach/3471107
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资源简介:
Reaction of 2-amino-3-(pyrrol-1-yl)-5,10,15-tris(4-tert-butylphenyl)corrolato copper(II) with arylaldehydes affords novel π-extended β,β′-pyrrolo(1,2-a)pyrazino-fused corroles via a Pictet–Spengler reaction. Corrole shows an unprecedented reaction pathway, leading to a mixture of phenyl-substituted and nonsubstituted pyrrolopyrazino annulated species as reaction products.
创建时间:
2016-07-11



