Protonation-Enhanced Reactivity of Triplet State in Dearomative Photocycloaddition of Quinolines to Olefins
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https://figshare.com/articles/dataset/Protonation-Enhanced_Reactivity_of_Triplet_State_in_Dearomative_Photocycloaddition_of_Quinolines_to_Olefins/15079010
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资源简介：
The
intermolecular dearomative cycloaddition of acidified bicyclic
azaarenes with olefins was recently reported. We report here the crucial
role of the acid in the dearomative photocycloaddition of quinolines
to olefins. Experimental and theoretical results show that the key
role of the protonation of quinolines is not to promote the energy
transfer but to enhance the reactivity of the triplet state of quinolines
toward olefins.
创建时间：
2021-07-29
