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Total Syntheses of Murrayamine E, I, and K

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https://figshare.com/articles/dataset/Total_Syntheses_of_Murrayamine_E_I_and_K/2161021
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We describe efficient synthetic routes to murrayamine A (mukoenine C), O-methylmurrayamine A, mahanine, O-methylmahanine, and murrayamine D and the first total syntheses of murrayamine E, I, and K. Key steps are a palladium-catalyzed construction of the carbazole framework and an annulation of the pyran ring, which is either catalyzed by phenylboronic acid or promoted by a Lewis acid.
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2016-02-13
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