Rapid Stereoselective Access to Key Pumiliotoxin Precursors from a Common Intermediate
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https://figshare.com/articles/dataset/Rapid_Stereoselective_Access_to_Key_Pumiliotoxin_Precursors_from_a_Common_Intermediate/3337843
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资源简介：
Epoxidation and dihydroxylation of 8-methyl-2,3,6,8a-tetrahydro-1H-indolizin-5-one proceeded from the
concave face with good selectivity and gave advanced
precursors for pumiliotoxin and allopumiliotoxin synthesis,
respectively. The origin of the selectivity is believed to be
stereoelectronic in nature and allows rapid entry to three
different pumiliotoxin classes from a common intermediate.
创建时间：
2004-05-28
