Rhodium-Catalyzed Three-Component Reaction between Silylacetylene and Two Ketenes Leading to 1,3-Enynes Bearing a Carboxylic Ester Group via Double Insertion of Ketenes
收藏Figshare2016-02-20 更新2026-04-29 收录
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https://figshare.com/articles/dataset/Rhodium_Catalyzed_Three_Component_Reaction_between_Silylacetylene_and_Two_Ketenes_Leading_to_1_3_Enynes_Bearing_a_Carboxylic_Ester_Group_via_Double_Insertion_of_Ketenes/2495695
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The first cross-reaction between a terminal silylacetylene and two ketene molecules leading to 1,3-enynes bearing a carboxylic ester group via double insertion of ketenes is achieved using a cationic rhodium complex catalyst. This reaction is applicable for various symmetrical and unsymmetrical ketenes with good stereoselectivities.
创建时间：
2016-02-20
