Synthesis and Characterization of a Cationic Ruthenium Complex Featuring an Unusual Bis(η<sup>2</sup>-BH) Monoborane Ligand
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The reaction of Cp*Ru(PiPr3)Cl with MesBH2 (Mes = 2,4,6-trimethylphenyl), followed by chloride abstraction with LiB(C6F5)4·2.5OEt2 (LiBF20), afforded the crystallographically characterized complex [Cp*Ru(PiPr3)(BH2Mes)]+B(C6F5)4−; notably, this represents the first reported cationic complex to feature an η2-BH monoborane ligand, as well as a rare example of bis(η2-BH) ligation.
创建时间：
2008-09-01
