Facile Control of the Charge Density and Photocatalytic Activity of an Anionic Indium Porphyrin Framework via in Situ Metalation
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https://figshare.com/articles/dataset/Facile_Control_of_the_Charge_Density_and_Photocatalytic_Activity_of_an_Anionic_Indium_Porphyrin_Framework_via_in_Situ_Metalation/2235766
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资源简介：
An
anionic indium porphyrin framework (UNLPF-10) consisting of
rare Williams β-tetrakaidecahedral cages was constructed using
an octatopic ligand linked with 4-connected [In(COO)4]− SBUs. Remarkably, the extent of indium metalation
of porphyrin macrocycles in UNLPF-10 can be facilely tuned in situ
depending on the M/L ratio during synthesis, resulting in a controllable
framework charge density and photocatalytic activity toward the selective
oxygenation of sulfides.
创建时间：
2016-02-16
