Synthesis of Oxacalixarene-Locked Bisporphyrins and Higher Oligomers
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https://figshare.com/articles/dataset/Synthesis_of_Oxacalixarene_Locked_Bisporphyrins_and_Higher_Oligomers/3239866
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资源简介:
The efficient one-step synthesis of oxacalixarene-bisporphyrins and higher oligomers from readily available starting
materials is described. The X-ray structure of one oxacalix[4]arene-locked cofacial bisporphyrin, prepared in 91% yield,
shows an 1,3-alternate conformation of the molecule with
partial overlap of the two porphyrin rings. 1H NMR data
supports a similar conformation in solution. The absorption
and emission spectra of oxacalixarene-porphyrins are briefly
discussed.
创建时间:
2016-05-05



