A Cyanide-Bridged Magnetically Switchable Cage with Encapsulated Water Molecules
收藏NIAID Data Ecosystem2026-03-09 收录
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A cage complex, H2O@[Co5Fe4], was found to encapsulate two water molecules during its self-assembly. The complex exhibited remarkable multifunctionality, combining magnetic switching from the thermal electron-transfer-coupled spin transition of the cage host and dipolar reorientational motion of the confined water, as evidenced by permittivity measurements, density functional theory calculations, and solid-state 2H NMR spectra.
创建时间:
2016-11-17



