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Unexpected De-Arylation of a Pentaaryl Fullerene

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NIAID Data Ecosystem2026-03-06 收录
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A triphenylamine-derived pentaaryl fullerene undergoes an unusual oxidative dearylation under basic conditions to give tetraarylated epoxy fullerene in high yield. The structure of the product was confirmed by single crystal X-ray diffraction. A mechanism is proposed to account for the loss of the addend and the subsequent formation of the epoxide group.

创建时间:
2016-02-26
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